Explain the Markovnikov hydrohalogenation of an alkene.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The hydrohalogenation of an alkene is an electrophilic addition reaction where a hydrogen halide ($HX$,where $X = Cl, Br, I$) adds across the double bond of an alkene to form an alkyl halide.
Markovnikov's rule,formulated in $1869$,states that when an unsymmetrical reagent adds to an unsymmetrical alkene,the negative part of the addendum (the nucleophilic part of the reagent) attaches itself to the carbon atom of the double bond that possesses the lesser number of hydrogen atoms.
Example: The reaction of propene $(CH_3-CH=CH_2)$ with $HBr$:
$CH_3-CH=CH_2 + HBr \rightarrow CH_3-CH(Br)-CH_3$ ($2$-Bromopropane,major product) and $CH_3-CH_2-CH_2Br$ ($1$-Bromopropane,minor product).
According to Markovnikov's rule,the $Br^-$ ion from $HBr$ attacks the central carbon atom (which has fewer hydrogen atoms),leading to the formation of $2$-Bromopropane as the major product.

Explore More

Similar Questions

What are the products obtained from the hydroboration-oxidation of propene and its hydration in the presence of dilute sulfuric acid,respectively?

What is $A$ in the following reaction?
$C_6H_5-CH_2-CH=CH_2 + HCl \rightarrow A$

Difficult
View Solution

The disappearance of the characteristic purple colour of $KMnO_4$ in its reaction with an alkene is the test for unsaturation. It is known as

What do you mean by olefin? Give an example.

The addition reaction of $1,3$-butadiene with bromine yields ........

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo